The plane is newly configured for a total of 214 seats in a two-class configuration.
The new jet will be based in Muscat, Oman.
Dubai firm Premier Composite Technologies (PCT) lands $16.5m, 10 year deal with Mubadala subsidiary.
Airline will become the launch customer of the A330-900neo.
Last week, Emirates had finalised a US$56bn order for 150 Boeing 777X aircraft.
Jordan-firm to provide base maintenance services for two Embraer 175 and three Airbus A330 aircraft.
Plane maker says the A330-800neo and A330-900neo will reduce fuel consumption by 14% per seat.
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